MobilNachhaltigTC Plattling MoMo
W. Schmidt, P. Bottke, Michael Sternad, P. Gollob, V. Hennige, M. Wilkening
Small Change—Great Effect: Steep Increase of Li Ion Dynamics in Li 4 Ti 5 O 12 at the Early Stages of Chemical Li Insertion
Chemistry of Materials, vol. 27, no. 5, pp. 1740-1750
Lithium titanate (LTO) is one of the most promising anode materials for large-scale stationary electrochemical storage of energy produced from renewable sources. Besides many other aspects, such as negligible formation of passivation layers and no volume expansion during lithiation, the success of LTO is mainly based on its ability to easily accommodate and release Li ions in a fully reversible way. This feature is tightly connected with Li self-diffusion. As yet, little information is available about microscopic Li diffusion properties and elementary steps of Li hopping at low intercalation levels, i.e., at values of x being significantly smaller than 1. Here, we used 7Li spin-locking NMR relaxometry to probe absolute hopping rates of LTO (homogeneous) solid solutions in quasi-thermodynamic equilibrium. As a result, the largest increase of Li diffusivity is observed when small amounts of Li are inserted. Strong Coulomb repulsions caused by the simultaneous occupation of neighboring 8a and 16c sites serve as an explanation for the enhanced Li diffusivity found. At even larger values of x, Li mobility slows down but is still much faster than in the host material with x = 0. Our results experimentally corroborate the outcome of recently published calculations on the DFT level focusing on both dynamic and structural aspects. The findings favor the formation of LTO solid solutions upon chemical lithiation; the steep increase in Li diffusivity found might also help with understanding the flat insertion potential observed.
Elektrotechnik und Medientechnik
M. Leghissa, B. Gromoll, J. Rieger, M. Oomen, H.-W. Neumüller, Reinhard Schlosser, H. Schmidt, W. Knorr, M. Meinert, U. Henning
Development and Application of Superconducting Transformers
Physica C: Superconductivity and its Applications, vol. 372-376, no. Part 3, pp. 1688-1693
Superconducting transformers are an important innovation for future power transmission and transportation systems. Powerful, lightweight, energy-saving and environmentally friendly they offer enormous benefits compared to their conventional counterparts. Siemens is developing a 1-MVA demonstrator transformer for laboratory testing, exhibiting innovative features like horizontal design, cabled-conductor windings and a closed cooling cycle with sub-cooled nitrogen. Being one of the most promising applications Siemens has started a programme towards the development of on-board transformers for electrical rail vehicles. This paper summarises world-wide efforts in the development of superconducting transformers and reports on the progress achieved at Siemens.